Coupled ion eye-safe laser

ABSTRACT

A coupled ion laser operating at a frequency determined by the energy levels characteristic of the coupling of a lanthanide or actinide group ion with an iron group ion in an orthoaluminate material, such as yttrium orthoaluminate, is described in which low threshold high efficiency starting operation at predetermined frequencies in the region of eye safety is provided.

b 1 1 Feb. 6, 1973 54 COUlPLED ION EYE-SAFE LASER 3,611,188 10 1971 Snitzer et al ..331/94.5 [75] Inventor: Marvin J. Weber, Wayland Mass 3,614,662 10 1971 Monchamp et al ..331 94.5

[73] Assignee: Raytheon Company, Lexington, Pri r Examiner Ronald L.Wiber1 MaSS- Assistant ExaminerR. .l. Webster [22] Filed: Feb'191971 Attorney-Milton D. Bartlett, Joseph D. Pannone,

Herbert W. Arnold and David M. Warren [21] App1.No.: 116,987

[57] ABSTRACT {52] 11.8. C1. ..33l/94.5, 252/3014, 330/43, A coupled ion laser operating at a frequency deter ,7 7 307/881 mined by the ener levels characteristic of the 51 1 (:1 11011021101310 l 1 P S I S coupling of a lanthanide or actinide group ion with an {58] Flew of Search 252/3Ol'4 iron group ion in an orthoaluminate material, such as 307/8 yttrium orthoaluminate, is described in which low threshold high efficiency starting operation at [56] References cued predetermined frequencies in the region of eye safety UNITED STATES PATENTS IS provldedr 3,591,517 7/1971 Van der Zicl et al. ..252/301.4 R 11 Claims, 3 Drawing Figures 5d BANDS e T, I \PuMP BANDS- 526 9 1 Z 2 l 2 g IE)! L 2 2' TIE 2l 1,l*"' T w 3 g l zll 3 131-155; W -2 l l 2P5 V3+ 3+ v3f-c 3'l' COUPLED ION EYE-SAFE LASER REFERENCE TO RELATED CASES Application, Ser. No. 886,617 of Roch R. Monchamp et al., now US. Pat. No. 3,614,662, Laser with a Monocrystalline YAlO zNd Active Medium filed Dec. 19, 1969, and application, Ser. No. 886,932 of Roch R. Monchamp et al., Single Crystalline (A Laser Host Material and Method for Making Same, filed Dec. 22, 1969, both of which are assigned to the same assignee as the present application, are hereby incorporated herein by reference.

BACKGROUND OF THE INVENTION This invention relates to compositions of matter suitable for laser use and to laser systems utilizing such compositions. More specifically, the invention relates generally to laser materials of the coupled ion type and particularly to devices generating coherent radiation in the wavelength region greater than 1.4 microns, the eye safe region.

In the prior art, lasers which were able to operate at frequencies in the eye safe region suffered from either low efficiency, high threshold starting, inability to operate at room temperature, and the requirement for cryogenic cooling; or from combinations of these problems. This is because lasers operate at fixed frequencies which are determined by the energy level scheme of the materials from which the lasing element is fabricated.

Possible eye damage from inadvertant exposure to coherent radiation producedby lasers operating in the region between 0.2 and 1.4 microns, in which region energy is transmitted by the eye and focused on the retina causing injury and possible blindness is an important consideration when using lasers in nonlaboratory environments where safety cannot be readily controlled; such as in range finders; illuminators and designators and in commercial applications such as surveying, construction alignment, and communications. Lasers of the prior art, which do not suffer from the above-mentioned deficiencies, operate in the noneyesafe region below 1.4 microns.

The most common optically pumped solid state lasers of the prior art are ruby and trivalent neodymium (Nd as a dopant in a host material of yttrium aluminum garnet (YAG) (Y Al O or glass. The operating frequency of the ruby laser is approximately 0.694 microns and that of the YAG laser is approximately 1.06 microns, hence their use constitutes an eye hazard.

An approach of the prior art to obtain eye safe laser operation has been the use of other lasing ions having laser transitions at longer wavelengths than either ruby or YAG, the most notable examples being trivalent erbium (Er as a dopant in glass, which has an operating frequency of 1.54 microns, trivalent erbium as a dopant in YAG which operates at 1.65 microns and trivalent holmium (110) as a dopant in YAG which operates at 2.1 microns.

Another prior art technique to obtain laser operation in the eye safe region has been to down-convert the emission of a laser, for example, the 1.06 micron Nd emission, to longer wavelengths using either parametric effects or a Raman active medium.

These techniques have serious shortcomings in that while operation at eyesafe frequencies is achieved, the operation is a low efficiency. For example, both Er and Ho lasers have relatively high thresholds of oscillation at room temperatures, and must be cryogenically cooled to achieve low threshold oscillation, the threshold of oscillation being the energy required to achieve a population inversion. If the threshold for laser action is high the laser must be pumped at higher energies, hence the overall efficiency of these lasers is low at room temperature. Since efficient operation at room temperature is desirable, there have been at tempts to improve the optical pumping efficiency thereby reducing the threshold of the Er and'Ho lasers by the addition of various codopant ions; however, there are few satisfactory codopants for Er. Other paramagnetic ions have been unsuitable for efficient, high-power laser operation in the eye safe region.

SUMMARY OF THE INVENTION The present invention relates to a laser material containing coupled ions to obtain laser action at wavelengths other than those possible in single laser ion noncoupled systems. More particularly, efficient laser operation in the eye safe region at room temperature in a coupled ion system using the material YR, AlM O is provided in which R is either a lanthanide group ion or an actinide group ion, M is an iron group ion and x is in the range of from greater than zero to less than one. Both of these ions are formed in a solid solution with an orthoaluminate such as yttrium-orthoaluminate to produce a coupling of the ions of R and M with resultant energy levels which provide laser operation at a wavelength which is shifted with respect to that of the ions individually. For eyesafe operation, R and M may, for example, be chosen to be trivalent cerium (Ge and trivalent vanadium (V*") to give efficient laser operation in the region between 1.30-1.55 microns Emission of coherent radiation in accordance with the principles of the present invention is produced by the stimulated energy decay of excited electrons from the fluorescent level of one element to a normally depopulated energy level above the ground state of another element. This ion coupling is caused by electron exchange between the two ions and a composite energy level scheme results, which is different from that of either element individually. Excitation is provided by optical pumping, and may be defined as the imparting of energy to electrons in one level to raise them to a higher level.

BRIEF DESCRIPTION OF THE DRAWINGS FIG. 1 is a graph of the relative transmissivity of the eye at various wavelengths of laser operation.

FIG. 2 is a diagram of the energy levels of trivalent chromium in isomorphic crystals of YAlO and of trivalent europium in EuAlO FIG. 3 is a diagram of the energy levels of individual trivalent vanadium and trivalent cerium ions in YAlO and of a coupled ion trivalent vanadium and trivalent cerium ion pair in YAlO DESCRIPTION OF THE PREFERRED EMBODIMENTS Referring now to FIG. 1, a graph of the relative ocular transmissivity of human eye to various laser operating frequencies is illustrated. Of course, the more energy the eye transmits and focuses on the retina, the greater the probability of eye damage becomes. It may be observed that the ocular transmissivity of the eye at wavelengths greater than 1.4 microns is at least six orders of magnitude smaller than the ocular transmissivity in the visible and near infrared regions between 0.2 and 1.4 microns. It is apparent that at laser operating frequencies greater than 1.4 microns, the eye transmits only a tiny fraction of the energy impinging on the cornea to the retina.

It has been observed by van der Ziel and Van Uitert and reported in the Physics Review Letters, Vol. 21,

1334 (1968), in an investigation of the emission spectrum of an europium aluminate crystal (EuAlO doped with chromium impurities that in addition to the R-line fluorescence characteristic of trivalent chromium (Cr a number of other lines appeared at longer wavelengths. This observation is more clearly understood with reference to FIG. 2, in which the energy levels of trivalent chromium (Cr) in the isomorphic crystal YAIO yttrium orthoaluminate and the energy levels of Eu in europium orthoaluminate (EuAlO are shown. The transition of Cr ions from the E energy level to the A energy level results in the E A R-line fluorescence characteristic of Cr. New emission lines at 7,000 to 10,000 Angstroms were observed, and these frequencies are correlated with a process by which an excited Cr ion in a E energy state decays to a A energy state and simultaneously excites a neighboring Eu ion to an excited F state as indicated by the arrows in FIG. 2. The energy difference of these two transitions appears as a photon in the wavelength range between 7,000 and 10,000 Angstroms. Since the emission process ends with the chromium ion in its ground state and an eurppium ion in an excited state, it is called europium-terminated chromium fluorescence. Flourescenc'e is the property of spontaneously emitting radiation as the result of absorption of radiation from some other source. The emitted radiation persists only as long as the material is subjected to radiation. I

The new energy levels occur as a result of a coupling between the rare earth ions, such as E-u and an ion group ion such as Cr. This coupling may, occur by magnetic, electric multipole, or exchange interactions. The emission lines are characteristic of a coupled ion pair and are similar to the pair spectra of coupled rare earth rare earth ions as reported by Varsanyi and Dieke, Physics Review Letters, Vol. 7, 442 (1961 and Cr Cr"" ions as reported by Schawlow et al., Physics Review Letters, Vol. 3, 502 (1959). The Eu and Cr ions in EuAlo zcr are coupled by exchange interactions. The additional long wavelength emission lines involve excitation of the europium system and therefore can be considered as exciton sidebands of the localized Cr exciton emission.

In addition to Cr rare earth pair emission in EuAlO :Cr pair emission has also been observed in TbAlO zCr YbAlo zCr, Eu Ga O zCr and Y, 3e A10 :Cr None of these systems fluoresce at wavelengths greater than 1.4 microns.

In accordance with the present invention, it has been discovered that laser action in materials containing coupled ions will occur in addition to the fluorescence of the prior art in combinations of ions of the rare earth lanthanides or actinides and the transition metal ions in an orthoaluminate, such as yttrium orthoaluminate and that the ion coupling of trivalent vanadium v and trivalent cerium Ce in particular produces an efficient laser operating in the eyesafe region. This class of materials is of the type Y R AI M O where R is an actinide or lanthanide which comprises the rare earth elements of atomic numbers 57 through and the actinide group elements, and where M comprises the iron transition group elements of atomic numbers 21 through 30. These ions are dispersed in a solid solution in a seeded melt with yttrium orthoaluminate using, for example, the Czochralski method of crystal growth as is described with reference to the aforesaid copending patent applications. The amount of R which is required is high, with x values which may approach one for an ion coupled system. This is because R must be uniformly dispersed in the solid solution to couple with M, which is much less populous.

Referring now to FIG. 3, the lower energy levels of V ions individually in YAlO and of Ce ions individually in YAlO are illustrated. It may be observed that V ions alone in YAIO form a three level laser system, with the third level comprising the pump bands centered at about 15,000, 25,000 and 30,000 wave numbers at the T T energy levels; the second level, a fluorescent level at 10,000 wave numbers and the ground state at zero wave numbers which is normally occupied by all electrons. To obtain lasing action from this system, a population inversion must be produced in a population of N ions of V thus at least N/2 ions must be pumped into the pump bands in order to decay into the second level. Lasing then would result from V ions decaying back from the second level to the first level.

When Ce' and V are present in YAIO and a small amount of V, less than approximately 1 percent, is substituted at the Al lattice sites, the Ce and V ions in the lattice are exchanged coupled by intervening oxygen ions. The approximate energy levels for a coupled V Ce ion pair is illustrated in simplified forms in FIG. 3. The zero order energy levels are approximately the sum of the single ion energy levels and the wave functions of the coupled ion states are simple products of single ion wave functions. Minor splittings and shifts of the energy levels and admixing of states, which are required in electric-dipole transitions are caused by the exchange interaction.

It has been discovered that the coupled ion system results in a four level laser with an additional normally unpopulated absorbtion band being introduced as a result of Ce and V exchange coupling at a series of energy bands centering approximately around wave number three. Operationally, a far more efficient laser system results since only a small number of ions must be pumped into the pump bands vis-a-vis the three level trivalent vanadium system. This is because electrons in the ground state at A, F,,, which are pumped into the pump bands at T and T of the fourth level and which decay to the third energy level at will produce stimulated emission immediately upon decay to the second level PA F,,, becaUse that level is normally unpopulated, hence a population inversion between levels three and two occurs when only a small number of electrons decay from level four to level three, and which results in a stimulated emission in a 1.31-1.53 micron region. Thus, it may be seen that the ion exchange phenomenon of the present invention enables lasing at this unexpected wave length and with greatly reduced energy pumping requirements.

In summary, V decays from the one,; energy 7 level to the A energy level, while Ce has stable states at the P and P levels. When Ce and V are ion coupled, new transitions at other energy levels occur. In particular, a group of transitions between thel EPF and l 'A P levels occur in the region between 1.3l.6 microns which includes the eye safe region. Selected frequencies within this range may be obtained by the variation of the optical cavity reflectivity or losses in a conventional manner such as variation in the dielectric constant on the cavity mirror or by filtering.

The stimulated emission obtained using cerium terminated vanadium fluorescence in a coupled ion system in accordance with the present invention constitutes a new laser material with emission falling approximately in the range of l .30l .55 microns, with the exact energy levels and wavelengths dependent upon the specific lattice. Additionally, this new energy level is unpopulated at ambient temperatures and is thus suitable for a four-level laser. As is apparent from FIG. 3, the F, levels of Ce are located at energies of approximately 3,000K. Assuming the stimulated emission probabilities to the P and P states are of the same order of magnitude, the P state will have the lower threshold for laser action. Furthermore, V" has broad absorption bands which are conducive to efficient optical pumping, instead of the narrow rare-earth energy levels in the cases of Er and Ho lasers.

Laser action in the eye safe region may be achieved by other combinations of vanadium and other rareearths. The host material must contain large quantities of rare-earth ions and be capable of being doped with up to 1 percent of trivalent vanadium. Other crystal phases of the rare-earth oxide-aluminum oxide system offer possible suitable lattice structures. These include RAlO (perovskite), 11 M 0 (garnet) and R Al O (2:1 compound); where R is a trivalent rare earth and V substitutes at Al sites in the lattice. These materials can be grown using the Czochralski technique.

As described in the beforementioned application of Monchamp et al., YAlO may be formed in a single large crystal by melting Y O and Al O in an inert atmosphere, seeding the melt with a YAlO crystal and slowly withdrawing the seed from the melt. The lattice sites of YAIO are such that coupling is stronger than throughout the solid solution. The second trivalent ion dopant, for example, vanadium is introduced into only a small percentage of the lattice sites (less than 1 percent) of the cerium doped YAIO however, this trivalent vanadium is always adjacent to some of the much more populous trivalent cerium. Xray analysis of this material indicates an orthorhombic unit cell; however, concentration of certain of the lanthanides, cerium and praseodymium in particular, approaching percent substitution for yttrium in an YAlO host would form a rhombohedral crystal structure. The Y, ,.R,,Al ,,M,,O coupled ion system is formed as a single crystal which is anisotropic. It is to be understood that other perovskite-like compounds isomorphic with YAlO may serve as host materials in a coupled ion laser system in accordance with the present invention.

While particular embodiments of the invention have been shown and described, various modifications thereof will be apparent to those skilled in the art, and therefore it is not intended that the invention be limited to the disclosed embodiments or details thereof and departures may be made therefrom within the spirit and scope of the invention as defined in the appended claims.

What is claimed is:

1. An optically pumped solid state laser system comprising:

an active laser medium having first and second ion coupled materials including trivalent vanadium ions; means for illuminating said solid state laser to produce population inversion in said medium; and

said medium providing an energy level characteristic that is the composite of the individual energy level characteristics of said first and second trivalent ion coupled materials.

2. A laser device in accordance with claim 1 wherein said first and second trivalent ions are trivalent vanadium and trivalent cerium respectively.

3. A laser device in accordance with claim 2 further characterized in that the laser emission is at a wavelength greater than approximately l.4 microns.

4. In combination:

a solid substantially single crystal laser medium;

means for producing a population inversion of electrons in an energy state of a first element of said medium; the stimulated emission of coherent radiation from said energy state being such that an energy transition occurs between said energy state of said first element and an energy state ofa second element;

said energy state of said second element being a normally depopulated level; and

at least one of said elements being trivalent vanadium ions.

5. A laser in accordance with claim 4 wherein said trivalent ions have an energy level characteristic that is the interaction composite of the individual energy level characteristics of said trivalent ion elements individually.

6. A laser in accordance with claim 5 wherein said trivalent ions are trivalent vanadium and trivalent ceri- 7. A laser in accordance with claim 6 further characterized in that the laser emission is at a wavelength greater than approximately 1.4 microns.

8. A laser device comprising:

an active laser medium consisting essentially of a trivalent lanthanide group element and trivalent vanadium in an yttrium orthoaluminate host:

a source of illumination incident upon said active medium for pumping said active medium; and

means for stimulating the emission of coherent radiation from said pumped active medium.

9. A laser device comprising:

an active laser medium comprising a trivalent actinide element and trivalent vanadium in an yttrium orthoaluminate host;

a source of illumination incident upon said active medium for pumping said active medium, and

means for stimulating the emission of coherent radiation from said pumped active medium.

10. A solid state laser operative at a frequency in the low transmissivity region of the eye comprising:

an active medium within the optical cavity consisting of trivalent vanadium and cerium ions in a yttrium orthoaluminate host;

a source of illumination incident upon said active medium for pumping said active medium; and means for stimulating the emission of coherent radiation from said pumped active medium.

11. A solid state laser in accordance with claim 10 wherein less than one percent of trivalent vanadium ions are substituted at aluminum lattice sites such that trivalent cerium ions and trivalent vanadium ions form coupled ion pairs which when pumped produce an emission at a frequency approximately greater than 1.4 microns.

UNITED STATES PATENT OFFICE CERTIFICATE OF CORRECTION Patent No. 3, 715,683 Dated February 6 1973 Inventor) Marvin J. Weber It is certified that error appears in the above-identified patent and that said Letters Patent are herebycorrected as shown below:

In the Specification Column 2 line 3, change ."a" to at Column 3, line 2, before "human" insert the Column 3, line 64, "EuAlO zCr should be EuAlO :Cr Column 3, line 64, "TbA1O Cr should be TbAlO3Z Cr Column 4, line 7, "v should be --v In the Claims Claim 4, column 6, line 58, "elements being trivalent" should be elements providing trivalent Signed and Sealed this thirteenth D ay Of January 1 9 76 [SEAL] A ttes t."

RUTH C. MASON C. MARSHALL DANN Attestmg Officer Commissioner ofParems and Trademarks UNITED STATES PATENT OFFICE CERTIFICATE OF CORRECTION Patent No. 5, 715,683 Dated February 6 1973 InVentor( Marl/in J. Weber It is certified that error appears in the above-identified patent and that said Letters Patent are hereby corrected as shown below:

In the Specification Column 2 line 3, change ."a" to at Column 3, line 2, before "human" insert the Column 3, line 64, "EuAlO Cr should be EuAlO :Cr Column 3, line 64, "TbAlO Cr should be TbA103: Cr Column 4, line 7, "v should be v In the Claims Claim 4, column 6, line 58, "elements being trivalent" should be elements providing trivalent Signed and Scaled this thirte n Day of January 1976 [SEAL] A ttes t."

RUTH C. MASON Arresting Officer 

1. An optically pumped solid state laser system comprising: an active laser medium having first and second ion coupled materials including trivalent vanadium ions; means for illuminating said solid state laser to produce population inversion in said medium; and said medium providing an energy level characteristic that is the composite of the individual energy level characteristics of said first and second trivalent ion coupled materials.
 2. A laser device in accordance with claim 1 wherein said first and second trivalent ions are trivalent vanadium and trivalent cerium respectively.
 3. A laser device in accordance with claim 2 further characterized in that the laser emission is at a wavelength greater than approximately 1.4 microns.
 4. In combination: a solid substantially single crystal laser medium; means for producing a population inversion of electrons in an energy state of a first element of said medium; the stimulated emission of coherent radiation from said energy state being such that an energy transition occurs between said energy state of said first element and an energy state of a second element; said energy state of said second element being a normally depopulated level; and at least one of said elements being trivalent vanadium ions.
 5. A laser in accordance with claim 4 wherein said trivalent ions have an energy level characteristic that is the interaction composite of the individual energy level characteristics of said trivalent ion elements individually.
 6. A laser in accordance with claim 5 wherein said trivalent ions are trivalent vanadium and trivalent cerium.
 7. A laser in accordance with claim 6 further characterized in that the laser emission is at a wavelength greater than approximately 1.4 microns.
 8. A laser device comprising: an active laser medium consisting essentially of a trivalent lanthanide group element and trivalent vanadium in an yttrium orthoaluminate host: a source of illumination incident upon said active medium for pumping said active medium; and means for stimulating the emission of coherent radiation from said pumped active medium.
 9. A laser device comprising: an active laser medium comprising a trivalent actinide element and trivalent vanadium in an yttrium orthoaluminate host; a source of illumination incident upon said active medium for pumping said active medium, and means for stimulating the emission of coherent radiation from said pumped active medium.
 10. A solid state laser operative at a frequency in the low transmissivity region of the eye comprising: an active medium within the optical cavity consisting of trivalent vanadium and cerium ions in a yttrium orthoaluminate host; a source of illumination incident upon said active medium for pumping said active medium; and means for stimulating the emission of coherent radiation from said pumped active medium. 